Table 1.
Parameter | Pa IDMS analyses | U IDMS analyses |
---|---|---|
Instrument | Nu-plasma HR multi-collector inductively-coupled plasma mass spectrometer | |
Collectors | 231Pa L2 Faraday cup, 233Pa axial Faraday | 233U L3 Faraday cup, 238U H1 |
cup | Faraday cup | |
Introduction system | Cetac Aridus II (Omaha, NE, USA) | |
Nebulizer | Cetac PFA Nebulizer | |
Nebulizer gas flow | 0.9 L/min | 0.9 L/min |
Solution uptake | 100 μL/min | 100 pL/min |
Mass bias CRM | CRM U010 [22] | CRM U010 |
Quality control CRM | U005-A [23] and CRMs 129-A [24] | CRM U005-A and CRM 112-A |
Corrections applied | Detector baseline, instrument background, detector gains, mass bias |
Revised uranium isotopic ratio values cited in [21] were used for CRMs U010 and U005-A