Table 2. Redox properties.

	E 1/2, V vs. SCE a
	E Ox2	E Ox1	E Red1	E Red2	E Red3
Ru		+1.15[1]	–1.44[1]	–1.63[1]	–1.85[1]
Ru2		+1.15[2]	–1.43[2]	–1.61[2]	–1.89[2]
Ru3		+1.17[3]	–1.45[3]	–1.60[3]	–1.92[3]
RuRe2	+1.36 irr	+1.14[1]	–1.41[3]	–1.67[1]	–1.88[1]
Ru2Re	+1.38 irr	+1.14[2]	–1.42[3]	–1.58[2]	–1.85[2]
[Ru(dmb)3]2+ b		+1.10[1]	–1.45[1]
[Re(dmb)(CO)3Cl] c		+1.36 irr	–1.43 [1]

^aElectrochemical properties measured at room temperature in MeCN containing 0.1 M TBAH. All values are obtained using the redox couple ferrocene/ferrocenium (395 mV vs. SCE in acetonitrile) as the internal reference. The numbers within parentheses refer to the number of exchanged electrons. Irr indicates an irreversible process: in this case, the E values reported in the table refer to peak potentials in pulse voltammetry experiments.

^bFrom ref. 27.

^cFrom ref. 24.