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Structures proposed for example hepta- and octasaccharide arabinoxyloglucans identified in CHEP based on MALDI-TOF/TOF MS/MS fragmentation pattern analyses [72,112]: SSG 4 and GSS 5 with m/z 1055.32 [M + Na]+; GSXG 6 with m/z 1085.33 [M + Na] +; SSGG 7 with m/z 1217.37 [M + Na]+. Absolute configurations are based on monosaccharide identities and the most common anomeric linkages reported for these types of structures and for cranberry oligosaccharides 2 and 3 [28].
