An electrodialysis cell with anion-exchange membranes (AEM) and cation-exchange membranes (CEM) forming desalination (DC) and concentration (CC) compartments (a); concentration profiles of a salt counterion in the diffusion boundary layer (DBL) at a CEM schematically shown at different current densities (b). “1”, “2”, and “3” indicate the points between which the potential drop is determined. δ′ is the effective DBL thickness; δ1, δ2, and δ3 are the thicknesses of the electroneutral zone, extended space charge region (SCR), and the equilibrium part of the electric double layer, respectively, of the DBL. Redrawn from [68].