Table 1.

The ¹H and ¹³C NMR data for 24-homoscalaranes 1 and 2 (CDCl₃).

C/H	1		2
	δH (J in Hz) a	δC Multiple b	δH (J in Hz) c	δC Multiple d
1	2.12 m; 0.48 ddd (12.8, 12.8, 3.2)	34.4, CH2	2.13 m; 0.80 m	33.8, CH2
2	1.50 m	17.8, CH2	1.44 m; 1.65 m	17.9, CH2
3	1.19 m; 1.43 m	41.6, CH2	1.18 m; 1.43 m	41.4, CH2
4		33.0, C		33.0, C
5	0.94 m	56.8, CH	0.95 br d (12.6)	56.8, CH
6	1.43 m	18.3, CH2	1.53 m	18.2, CH2
7	1.03 m; 1.82 ddd (12.8, 3.2, 3.2)	42.2, CH2	0.96 m; 1.91 ddd (13.2, 3.6, 3.6)	42.1, CH2
8		37.8, C		38.7, C
9	1.50 m	49.3, CH	1.26 m	62.8, CH
10		41.7, C		42.8, C
11	2.07 m	24.9, CH2	2.62 dd (12.6, 1.8); 3.34 dd (14.4, 12.6)	39.0, CH2
12	4.77 br s	75.7, CH		221.9, C
13		38.9, C		52.8, C
14	1.31 m	52.2, CH	1.21 m	58.0, CH
15	2.27 m	23.3, CH2	1.65 m; 1.94 ddd (12.6, 4.2, 1.8)	30.1, CH2
16	6.90 br s	139.7, CH	3.53 ddd (10.8, 10.8, 4.8)	72.7, CH
17		137.9, C	3.22 dd (12.0, 10.8)	54.8, CH
18	3.79 br s	48.0, CH	3.18 d (12.0)	51.3, CH
19	0.75 s	21.9, CH3	0.76 s	21.7, CH3
20	0.86 s	33.8, CH3	0.87 s	33.7, CH3
21	1.16 s	16.1, CH3	1.30 s	16.4, CH3
22	3.85 d (11.6); 4.02 d (11.6)	62.9, CH2	3.93 dd (11.4, 1.2); 4.08 d (11.4)	62.7, CH2
23	0.96 s	15.5, CH3	1.34 s	15.3, CH3
24		199.3, C		212.6, C
25		175.1, C		172.4, C
26	2.29 s	25.3, CH3	2.40 s	33.4, CH
OAc-12		170.4, C
	2.14 s	21.5, CH3

^a 400 MHz. ^b 100 MHz. ^c 600 MHz. ^d 150 MHz.