Table 2.

The ¹H and ¹³C NMR data for 24-homoscalaranes 3 and 4 (CDCl₃).

C/H	3		4
	δH (J in Hz) a	δC Multiple b	δH (J in Hz) c	δC Multiple d
1	2.16 m; 0.80 m	34.0, CH2	2.01 m; 0.52 ddd (13.8, 13.8, 3.0)	34.7, CH2
2	1.63 m	18.4, CH2	1.63 m	18.2, CH2
3	1.18 m; 1.43 m	41.7, CH2	1.15 ddd (9.0, 9.0, 4.2); 1.43 m	41.5, CH2
4		33.0, C		33.0, C
5	1.05 m	56.8, CH	1.01 dd (13.8, 3.6)	57.1, CH
6	1.56 m; 1.91 m	16.9, CH2	1.56 m; 1.93 m	17.0, CH2
7	1.10 m; 1.89 m	42.0, CH2	1.11 ddd (12.0, 12.0, 4.2); 1.92 m	41.9, CH2
8		37.6, C		37.5, C
9	1.56 m	52.3, CH	1.26 m	53.2, CH
10		41.8, C		40.2, C
11	1.89 m; 2.18 m	27.1, CH2	1.99 m; 2.20 m	23.3, CH2
12	4.60 br s	69.9, CH	5.54 t (3.0)	73.8, CH
13		40.2, C		38.4, C
14	1.60 m	50.0, CH	1.55 m	51.2, CH
15	2.18 m; 2.35 m	24.1, CH2	2.23 m; 2.39 m	24.0, CH2
16	1.46 m; 1.56 m	18.0, CH2	1.60 m	18.0, CH2
17		165.2, C		163.6, C
18		133.5, C		132.6, C
19	0.78 s	21.8, CH3	0.83 s	21.9, CH3
20	0.86 s	33.9, CH3	0.89 s	33.7, CH3
21	1.08 s	16.3, CH3	0.98 s	16.4, CH3
22	3.92 d (11.5); 4.05 d (11.5)	63.0, CH2	4.15 dd (12.0, 1.2); 4.58 d (12.0)	64.7, CH2
23	1.13 s	21.7, CH3	1.19 s	21.3, CH3
24	4.79 q (6.5)	78.2, CH	4.78 q (6.0)	77.7, CH
25		172.6, C		171.1, C
26	1.37 d (6.5)	18.5, CH3	1.36 d (6.0)	18.6, CH3
OAc-12				169.9, C
			1.97 s	21.2, CH3
OAc-22				170.9, C
			2.07 s	21.2, CH3

^a 500 MHz. ^b 125 MHz. ^c 600 MHz. ^d 150 MHz.