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. Author manuscript; available in PMC: 2020 Sep 25.
Published in final edited form as: J Am Chem Soc. 2019 Sep 10;141(38):15433–15440. doi: 10.1021/jacs.9b08185

Figure 11.

Figure 11.

Possible mechanism for the nickel/bis(oxazoline)-catalyzed enantioconvergent Kumada coupling of an α-bromoketone with a Grignard reagent. Intermediates that have been isolated are boxed. For the sake of simplicity, all elementary steps are depicted as being irreversible.