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. 2020 Mar 16;11:1409. doi: 10.1038/s41467-020-15141-y

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© The Author(s) 2020

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 5 — a Free energy profiles for HER (dashed lines) and CO₂RR (solid lines) on M1O₄ complexes of PcCu-O₈-Zn at U = 0.55 V. b Schematic HER and CO₂RR reaction process of PcCu-O₈-Zn.