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. 2020 Mar 13;6(3):e03590. doi: 10.1016/j.heliyon.2020.e03590

Table 2.

Selected compounds identified in extracts of produced water from the Bakken and Three Forks Formations with estimated concentration ranges.

Compounds by class Samples with detection (From Table 1) Estimated Concentration Range (μg/L)
1. Polycyclic aromatic hydrocarbons
Naphthalene 01-10,12 <1.0-1.2
1-Methyl-naphthalene 01-10,12 1.1-2.3
2-Methyl-naphthalene 01-10,12 <1.0-1.5
1,6-Dimethyl-naphthalene 01
1.6

2. Aromatics

p-Xylene 01-09,12 5.1-9.7
Mesitylene 01-09,12 2.3-8.0
Trimethyl-benzenes (not including Mestiylene) 01-03,05,09,12 1.8-3.9
N-Phenyl-formamide
07 11.5

3. Phenols

Phenol 01-10,12 12-46
p-Cresol 01-09,12 4.9-19
2-Methyl-phenol 01-05,07-09,12 4.5-18
Dimethyl-phenols 01-03,12 <1.0-3.7
2,2′-Methylenebis-phenol 04-09 3.8-28
4,4′-Methylenebis-phenol 04-10 8.3-63
4,4’-(1-Methylethylidene)bis-phenol 05 2.4

4. Glycol ethers

2-Butoxy-ethanol 10 >400
2-Phenoxy-ethanol 06,07 1.8-11
1-(2-methoxy-1-methylethoxy)-2-propanol (all isomers) 06,07 57-75

5. Alkanes

Dodecane 01 1.4
Tetradecane 01 1.4
Pentadecane 01 1.5
Hexadecane 01 1.7
Heptadecane 01 1.1
Octadecane
01 1.0

6. Cyclic non-aromatics and heterocycles

2-Methyl-2-cyclopenten-1-one 01,03,05-07 3.1-37
3-Methyl-2-cyclopenten-1-one 02-04,06-09,12 3.1-17
3-Ethyl-2-hydroxy-2-cyclopenten-1-one 04,07,08 1.2-9.5
3-Methyl-1,2-cyclopentanedione 04,07-09 6.8-54
Tetrahydro-2,5-dimethyl-furan 12 5.0
Dihydro-5-methyl-2(3H)-furanone 02,03 3.2-3.8
5,6,7,8-Tetrahydro-N,N-dimethyl-1-naphthalenamine 01,03,12 1.1-2.5
1,2,3,4,5,6,7,8-Octahydro-acridine 01 <1.0
6(5H)-Phenanthridinone 08 1.6
4-Methyl-2-(2-methyl-1-propenyl)-pyridine 01-03,12 1.8-4.0
3-Benzyl-6-isopropyl-2,5-piperazinedione 04,09 4.4-4.6
Hexahydro-3-(2-methylpropyl)-pyrrolo[1,2-a]pyrazine-1,4-dione 04,07-09 4.9-13
Hexahydro-3-(phenylmethyl)-pyrrolo[1,2-a]pyrazine-1,4-dione
04,06-08 1.6-12

7. Other Compounds

Octanoic acid 09 1.9
9-Octadecenamide 03 2.3
N,N-Dimethyloctylamine 01,02 4.9-17.7

Sample 11 was not collected for extractable hydrocarbon analysis.