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Oleocanthal (OLC) and its metabolites identified in lumen and plasma samples using an LTQ–Orbitrap.
| Compound | RT (min) | Accurate Mass | Major Fragments | Error (mDa) | Molecular Formula |
|---|---|---|---|---|---|
| OLC | 5.8 | 303.1230 | 285.1125/179.0708 | 0.48 | C17H19O5 |
| OLC + OH | 6.49 | 319.1180 | 153.0271/183.0665 | 0.16 | C17H19O6 |
| OLC + H2O | 6.36 | 321.1344 | 201.0759/183.0665 | 0.88 | C17H21O6 |
| OLC + H2 + glucuronide | 5.83 | 481.1719 | 217.0859/185.0509 | 0.05 | C23H29O11 |
| OLC+ H2O + glucuronide | 5.74 | 497.1666 | 321.1344/201.0759 | 0.17 | C23H29O12 |
