Table 3.
Mycotoxin | Precursor ion (m/z) |
Product ions a (m/z) |
CE a,b (eV) | CV c (V) | Retention time (min) |
LOD d (ng/mL) | LOQ e (ng/mL) |
---|---|---|---|---|---|---|---|
DON | 297.0 | 249.0/231.0 | 9/9 | 40 | 3.99 | 0.2 | 0.4 |
DON-3-glucoside | 459.1 | 168.1/132.0 | 10/9 | 15 | 3.90 | 0.3 | 0.6 |
DON-3-glucuronide/ DON-15-glucuronide |
471.0 | 113.0/193.0 | 30/24 | 60 | 3.65/3.78 | 0.5 | 1.0 |
3-ADON/15-ADON | 339.0 | 231.0/203.1 | 15/9 | 15 | 5.69 | 0.1 | 0.2 |
DOM-1 | 281.1 | 215.1/233.1 | 9/9 | 40 | 4.83 | 0.6 | 1.2 |
13C15 DON | 311.9 | 262.9/130.5 | 10/10 | 30 | 3.99 |
a Values are given as quantifier ion/qualifier ion; b CE: collision energy; c CV: cone voltage; d LOD: limit of detection; e LOQ: limit of quantification.