Table 8. Solubilities of Solutions in the Quaternary System NaCl–Na2CO3–NaOH–H2O at T = 363.15 K and P = 88.94 kPaa.
| liquid mass % |
dry salt
(liquid) mass % |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| no. | NaOH | Na2CO3 | NaCl | H2O | NaOH | Na2CO3 | NaCl | H2O mass (g/100 g dry salt) | solution density ρ/g·cm–3 | equilibrium phase solidsb |
| 1 | 0.00 | 0.00 | 27.80 | 72.20 | 0.00 | 0.00 | 100.00 | 259.71 | 1.1723 | Cl |
| 2 | 68.87 | 0.00 | 2.87 | 28.26 | 96.00 | 0.00 | 4.00 | 39.39 | 1.5831 | Cl + OH |
| 3 | 76.28 | 0.00 | 0.00 | 23.72 | 100.00 | 0.00 | 0.00 | 31.10 | 1.5884 | OH |
| 4 | 48.79 | 0.55 | 0.00 | 50.66 | 98.88 | 1.12 | 0.00 | 102.68 | 1.4696 | OH + C |
| 5(E1) | 51.00 | 2.05 | 4.01 | 42.94 | 89.38 | 3.59 | 7.03 | 75.26 | 1.5215 | C + OH + Cl |
| 6 | 36.51 | 1.95 | 3.64 | 57.90 | 86.72 | 4.64 | 8.64 | 137.52 | 1.3868 | C + Cl |
| 7(E2) | 34.21 | 1.69 | 4.34 | 59.76 | 85.02 | 4.20 | 10.78 | 148.51 | 1.3680 | C + C1 + Cl |
| 8 | 17.14 | 10.99 | 0.00 | 71.87 | 60.93 | 39.07 | 0.00 | 255.49 | 1.2339 | C + C1 |
| 9 | 0.00 | 30.50 | 0.00 | 69.50 | 0.00 | 100.00 | 0.00 | 227.87 | 1.3112 | C1 |
| 10 | 0.00 | 9.97 | 21.09 | 68.94 | 0.00 | 32.10 | 67.90 | 221.96 | 1.2031 | C1 + Cl |
| 11 | 8.65 | 3.17 | 15.54 | 72.64 | 31.61 | 11.57 | 56.82 | 265.62 | 1.2084 | C1 + Cl |
| 12 | 16.42 | 2.57 | 10.71 | 70.30 | 55.28 | 8.67 | 36.05 | 236.73 | 1.2453 | C1 + Cl |
| 13 | 28.46 | 3.15 | 9.47 | 58.92 | 69.29 | 7.65 | 23.06 | 143.42 | 1.3418 | C1 + Cl |
| 14 | 24.67 | 1.58 | 7.14 | 66.61 | 73.88 | 4.73 | 21.39 | 199.44 | 1.2940 | C1 + Cl |
| 15 | 30.11 | 1.65 | 4.6 | 63.64 | 82.81 | 4.54 | 12.65 | 175.06 | 1.3286 | C1 + Cl |
Standard uncertainties u are u(T) = 0.1 K, u(P) = 0.5 kPa, and ur(Na2CO3) = ur(NaCl) = ur(NaOH) = 0.05.
Abbreviations: OH, NaOH; Cl, NaCl; C, Na2CO3; and C1, Na2CO3·H2O.