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. 2020 Mar 20;10:5149. doi: 10.1038/s41598-020-62059-y

Table 4.

Thermodynamic parameters for the adsorption of p-nitrophenol onto biochar samples obtained at different pyrolysis temperatures.

Sample lnK T (K) ΔG (kJ/mol) ΔH (kJ/mol) ΔS (J/(mol∙K))
PC300 1.5240 288 −3.6491 13.068 49.908
1.7410 298 −4.3136
1.8776 308 −4.8081
PC400 2.2470 288 −5.3803 17.309 78.503
2.3841 298 −5.9071
2.7187 308 −6.9622
PC500 2.7548 288 −6.5964 25.747 112.913
3.3407 298 −8.2768
3.4480 308 −8.8294
PC600 1.8776 288 −4.4959 37.218 144.799
2.3841 298 −5.9071
2.8873 308 −7.3936
PC700 2.1546 288 −5.1591 42.337 164.577
2.6225 298 −6.4977
3.3056 308 −8.4647