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. Author manuscript; available in PMC: 2020 Mar 22.
Published in final edited form as: J Org Chem. 2018 Oct 17;83(21):13256–13266. doi: 10.1021/acs.joc.8b02070

Table 3.

13C NMR for trichophycins C-E (2-4) (200 MHz, CDCl3)

2 3 4 Δδ 13C (2-3; 2-4)

pos δC, type δC, type   δC, type
1 119.2, CH 119.2, CH 119.2, CH 0.0; 0.0
2 130.7, CH 130.7, CH 130.7, CH 0.0; 0.0
3 35.0, CH2 35.0, CH2 35.1, CH2 0.0; −0.1
4 74.8, CH 74.8, CH 74.8, CH 0.0; 0.0
5 35.8, CH 35.8, CH 35.8, CH 0.0; 0.0
6 39.8, CH2 39.7, CH2 39.8, CH2 0.1; 0.0
7 30.1, CH 30.2, CH 30.2, CH −0.1; −0.1
8 31.5, CH2 31.6, CH2 31.6, CH2 −0.1; −0.1
9 34.0, CH2 34.1, CH2 34.1, CH2 −0.1; −0.1
10 69.2, CH 69.2, CH 69.3, CH 0.0; −0.1
11 42.8, CH2 43.1, CH2 43.1, CH2 −0.3; −0.3
12 138.6, C 138.9, C 138.8, C −0.3; −0.2
13 36.3, CH2 29.4, CH2 29.4, CH2
14 138.2, C 26.1, CH2 25.9, CH2
15 128.7, CH 18.4, CH2 19.6, CH2
16 128.6, CH 83.9, C 79.7, C
17 126.6, CH 68.8, CH 38.4, C
18 128.6, CH 115.4, CH 115.4, CH
19 128.7, CH 20.7, CH3 20.7, CH3
20 115.5, CH 15.7, CH3 15.8, CH3
21 20.6, CH3
22 15.7, CH3