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. 2014 Dec 9;301:24–48. doi: 10.1016/j.ccr.2014.12.002

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Copyright © 2014 Elsevier B.V. All rights reserved.

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Fig. 4 — Analogy between phosphate and vanadate. Besides monovanadate being structurally similar to phosphate, the acid-base equilibria operating and other types of reactions (e.g. V and/or P ‘ester’ formation) are similar. However, there are also some structural and pK_a differences (see text) [6], [148].