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Advances in the development of metal–organic frameworks (MOFs). Important milestones include the development of an extended coordination compound “Prussian Blue” and the porous coordination polymer Cu[C(C6H4CN)4], the construction of robust MOF-5 and ultraporous MIL-101, the further development of ultrastable UiO-66 and flexible MIL-88, and the evolution of heterarchical MOFs with enhanced diversity and hierarchical MOFs with controllable internal sequences and architectures.
