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. 2020 Mar 18;16:415–444. doi: 10.3762/bjoc.16.40

Table 3.

NIR sensitized photo-ATRP of MMA under different experimental conditions (L: tris(2-pyridylmethyl)amine) with different sensitizers (Sens) [81].

Sens [MMA]/[EBPA]/[CuBr2]/[L]/[Sens] Cu(II)
(ppm)
time
(h)
conversion
(%)
Mn
(g·mol−1)
Mw/Mn

48 300/1/0.15/1.65/1.5 500 2 27.2 14000 1.47
48 300/1/0.03/0.135/0.3 100 24 44.3 13000 1.17
48 300/0/0.03/0.135/0.3 100 24
48 300/1/0.03/0.135/0 100 24
48 300/1/0/0/0.3 100 24 26.7 400000 2.47
78 300/1/0.03/0.135/0.3 100 24
24 300/1/0.03/0.135/0.3 100 24
93 300/1/0.03/0.135/0.3 100 24
94 300/1/0.03/0.135/0.3 100 24