Table 2. Decay Characteristics of C(t) of C-490 in n-Propanol, Bulk Solvent, and Reverse Micelles of 12-5-12, 12-6-12, and 12-8-12 at Varying Wo.
pure and mixed solvents | |||||
---|---|---|---|---|---|
solvents | α1s | τ1s (ps) | α2s | τ2s (ps) | ⟨τs⟩ (ps) |
bulk solvent | 0.33 ± 0.07 | 959.26 ± 0.17 | 0.67 ± 0.07 | 256.92 ± 0.02 | 493.83 |
n-propanol | 1.00 | 139.92 ± 0.01 | 139.92 |
12-5-12 | |||||||
---|---|---|---|---|---|---|---|
Wo | α1s | τ1s (ps) | α2s | τ2s (ps) | ⟨τs⟩ (ps) | missing component | Δυ̅a (cm–1) |
2 | 0.15 ± 0.04 | 943.27 ± 0.32 | 0.85 ± 0.04 | 281.12 ± 0.01 | 380.44 | 0.13 | 1140 |
5 | 0.18 ± 0.02 | 912.64 ± 0.42 | 0.82 ± 0.03 | 243.12 ± 0.01 | 363.63 | 0.21 | 1046 |
10 | 0.37 ± 0.01 | 644.31 ± 0.01 | 0.63 ± 0.01 | 145.73 ± 0.01 | 330.20 | 0.31 | 956 |
15 | 0.29 ± 0.01 | 754.63 ± 0.01 | 0.71 ± 0.01 | 140.47 ± 0.01 | 318.58 | 0.38 | 882 |
20 | 0.24 ± 0.01 | 769.14 ± 0.02 | 0.76 ± 0.01 | 133.29 ± 0.01 | 285.89 | 0.39 | 886 |
25 | 0.13 ± 0.01 | 964.79 ± 0.12 | 0.87 ± 0.01 | 155.78 ± 0.01 | 260.95 | 0.44 | 828 |
12-6-12 | |||||||
---|---|---|---|---|---|---|---|
Wo | α1s | τ1s (ps) | α2s | τ2s (ps) | ⟨τs⟩ (ps) | missing component | Δυ̅a (cm–1) |
2 | 0.29 ± 0.01 | 967.06 ± 0.04 | 0.71 ± 0.01 | 243.41 ± 0.01 | 453.27 | 0.06 | 1162 |
5 | 0.27 ± 0.02 | 906.78 ± 0.04 | 0.73 ± 0.01 | 262.38 ± 0.01 | 436.37 | 0.11 | 1126 |
10 | 0.18 ± 0.02 | 1000.48 ± 0.05 | 0.82 ± 0.02 | 233.18 ± 0.01 | 371.29 | 0.23 | 1045 |
15 | 0.21 ± 0.02 | 867.61 ± 0.04 | 0.79 ± 0.02 | 221.31 ± 0.01 | 357.03 | 0.30 | 1001 |
20 | 0.20 ± 0.01 | 925.28 ± 0.05 | 0.80 ± 0.01 | 172.00 ± 0.01 | 322.26 | 0.42 | 872 |
25 | 0.19 ± 0.01 | 840.78 ± 0.03 | 0.81 ± 0.02 | 158.30 ± 0.01 | 287.97 | 0.52 | 729 |
12-8-12 | |||||||
---|---|---|---|---|---|---|---|
Wo | α1s | τ1s (ps) | α2s | τ2s (ps) | ⟨τs⟩ (ps) | missing component | Δυ̅a (cm–1) |
2 | 0.19 ± 0.03 | 1149.60 ± 0.09 | 0.81 ± 0.02 | 335.54 ± 0.01 | 490.21 | 0.15 | 1011 |
5 | 0.33 ± 0.02 | 948.58 ± 0.03 | 0.77 ± 0.01 | 198.25 ± 0.01 | 465.68 | 0.22 | 944 |
10 | 0.44 ± 0.01 | 812.52 ± 0.02 | 0.56 ± 0.01 | 137.06 ± 0.01 | 434.26 | 0.34 | 818 |
15 | 0.27 ± 0.01 | 1013.60 ± 0.03 | 0.73 ± 0.01 | 206.77 ± 0.01 | 424.61 | 0.37 | 837 |
20 | 0.39 ± 0.01 | 814.53 ± 0.02 | 0.61 ± 0.01 | 128.96 ± 0.01 | 396.33 | 0.57 | 602 |
25 | 0.32 ± 0.01 | 741.05 ± 0.01 | 0.68 ± 0.01 | 101.86 ± 0.01 | 306.40 | 0.60 | 571 |
Δυ̅ = υ̅(0) – υ̅(∞).