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. 2020 Mar 17;5(12):6738–6753. doi: 10.1021/acsomega.0c00035

Table 3. Rotational Relaxation Time of C-490 in n-Propanol, Bulk Solvent, and Reverse Micelles of 12-s-12, 2Br–

pure and mixed solvents
solvents α1r τ1r (ps) α2r τ2r (ps) ⟨τr⟩ (ps) χ2
bulk solvent 1.00 278 ± 27     278 1.10
n-propanol 1.00 356 ± 43     356 1.07
12-5-12
Wo α1r τ1r (ps) α2r τ2r (ps) ⟨τr⟩ (ps) χ2
2 0.06 ± 0.01 6211 ± 498 0.94 ± 0.03 448 ± 65 794 1.04
5 0.06 ± 0.01 6469 ± 511 0.94 ± 0.03 411 ± 48 774 1.02
10 0.05 ± 0.01 6334 ± 502 0.95 ± 0.04 387 ± 58 684 1.10
15 0.04 ± 0.01 6725 ± 525 0.96 ± 0.04 367 ± 62 621 1.06
20 0.03 ± 0.01 5630 ± 478 0.97 ± 0.04 377 ± 59 535 1.04
25 0.03 ± 0.01 4655 ± 470 0.97 ± 0.04 340 ± 58 469 1.04
12-6-12
Wo α1r τ1r (ps) α2r τ2r (ps) ⟨τr⟩ (ps) χ2
2 0.10 ± 0.01 4456 ± 438 0.90 ± 0.03 441 ± 63 843 1.07
5 0.07 ± 0.01 5573 ± 435 0.93 ± 0.04 457 ± 63 815 0.97
10 0.06 ± 0.01 5954 ± 477 0.94 ± 0.03 412 ± 58 745 1.07
15 0.04 ± 0.01 7203 ± 553 0.96 ± 0.04 418 ± 64 689 0.99
20 0.04 ± 0.01 6002 ± 485 0.96 ± 0.04 400 ± 61 624 1.09
25 0.03 ± 0.01 7286 ± 580 0.97 ± 0.04 376 ± 58 583 0.99
12-8-12
Wo α1r τ1r (ps) α2r τ2r (ps) ⟨τr⟩ (ps) χ2
2 0.07 ± 0.01 6848 ± 529 0.93 ± 0.04 538 ± 84 980 1.07
5 0.07 ± 0.01 6638 ± 519 0.93 ± 0.04 492 ± 73 922 1.06
10 0.06 ± 0.01 6918 ± 549 0.94 ± 0.03 489 ± 67 875 1.07
15 0.05 ± 0.01 7306 ± 560 0.95 ± 0.03 437 ± 68 780 1.02
20 0.05 ± 0.01 6910 ± 548 0.95 ± 0.04 423 ± 65 747 1.08
25 0.05 ± 0.01 5778 ± 520 0.95 ± 0.04 399 ± 68 668 1.07