. Author manuscript; available in PMC: 2020 Aug 17.

Published in final edited form as: Tetrahedron. 2016 Nov 16;72(52):8603–8609. doi: 10.1016/j.tet.2016.11.040

Table 7. Instrumentation parameter for ICPMS and ESMS optimized for peptide quantification.

Instruments Parameter	Value
ICP-MS	Agilent 8800
Mode	Organic (Pt- cones, organic torch, PFA- micronebulizer)
HF	1600W
Nebulizer-type	Microflow
Nebulizer gas	0.91 L/min
Optional gas	6 % oxygen (80:20 Ar:O₂)
Plasma gas	0.98 Lmin
Coolant gas	15.5 L/min
Reaction cell gas	O₂
Reaction cell gas flow	0.3 mL/min
ESI – MS:	LTQ Orbitrap Discovery (Thermo Scientific)
Mode	Positive
Resolution	30,000
MSMS mode	automatic
Ionspray voltage	4.5 KV