Table 2.
Sample | Core/Pol a) | Mw [kg mol−1] b) | Ð | Generation of core | Molar ratio Pol : core | No. of chains on core | Dh (int.) c) [nm] |
---|---|---|---|---|---|---|---|
S8 | Dendron/P1-TT | 137 | 1.01 | G4 | 8 : 1 | 7.2 | 16.1±0.6 |
S31 | Dendron/P2-TT | 222 | 1.06 | G4 | 8 : 1 | 5.3 | 19.5±0.5 |
S18 | Dendrimer/P1-Prg | 149 | 1.06 | G3 | 8 : 1 | 7.6 | 16.7±0.3 |
S41 | Dendrimer/P2-Prg | 213 | 1.13 | G3 | 8 : 1 | 5.0 | 20.4±1.1 |
Type of dendritic core used (Dendron = bisMPA dendron, dendrimer = bisMPA dendrimer,), Pol = semitelechelic polymer precursor used for star-like polymer formulation
Molecular weight Mw and dispersity Ð were determined by SEC using multi-angle light scattering and refractive index detectors.
Hydrodynamic diameter was measured by DLS in 0.15M NaCl