Table 1.
T/K |
|
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
w | |||||||||||
1 | 0.8994 | 0.7988 | 0.7005 | 0.5992 | 0.4998 | 0.3999 | 0.3001 | 0.2013 | 0.0991 | 0 | |
278.15 | 0.03788 | 0.08134 | 0.1308 | 0.1892 | 0.2436 | 0.2783 | 0.3223 | 0.3731 | 0.4335 | 0.5198 | 0.5803 |
283.15 | 0.05168 | 0.1124 | 0.1847 | 0.2601 | 0.3143 | 0.3734 | 0.4277 | 0.4967 | 0.5831 | 0.6939 | 0.7755 |
288.15 | 0.07109 | 0.1513 | 0.2424 | 0.3362 | 0.4317 | 0.5013 | 0.5778 | 0.6679 | 0.7811 | 0.9040 | 1.039 |
293.15 | 0.09523 | 0.1998 | 0.3232 | 0.4470 | 0.5496 | 0.6577 | 0.7549 | 0.8748 | 1.023 | 1.197 | 1.354 |
298.15 | 0.1278 | 0.2652 | 0.4275 | 0.5893 | 0.7267 | 0.8507 | 0.9801 | 1.127 | 1.319 | 1.528 | 1.741 |
303.15 | 0.1710 | 0.3457 | 0.5433 | 0.7411 | 0.9312 | 1.076 | 1.254 | 1.432 | 1.665 | 1.939 | 2.190 |
308.15 | 0.2231 | 0.4424 | 0.7165 | 0.9509 | 1.152 | 1.346 | 1.553 | 1.819 | 2.085 | 2.422 | 2.732 |
313.15 | 0.2929 | 0.5844 | 0.9178 | 1.204 | 1.463 | 1.698 | 1.988 | 2.242 | 2.584 | 2.981 | 3.347 |
318.15 | 0.3791 | 0.7427 | 1.179 | 1.547 | 1.891 | 2.113 | 2.424 | 2.756 | 3.158 | 3.630 | 4.053 |
Standard uncertainties u are u(T) = 0.02 K, u(p) = 0.45 kPa; Relative standard uncertainty ur is ur (x) = 0.045. Solvent mixtures were prepared by mixing different masses of the solvents with relative standard uncertainty ur(w) = 0.0002. w represents the mass fraction of methanol in mixed solvents of methanol (w) + water (1 − w).