Table 1.
Entry | Acrylamide 11 | Ratio of trans-9/cis-9 | Yield (%) |
---|---|---|---|
R | |||
A | 81:19 | trans-9a (63)a + cis-9a (11)a + trans-9a and cis-9a (11)b | |
B | 84:16 | trans-9b (71)a + cis-9b (14)a + trans-9b and cis-9b (2)b | |
C | 79:21 | trans-9c (67)a + cis-9c (19)a + trans-9c and cis-9c (5)b | |
D | 79:21 | trans-9d (33)a + cis-9d (8)a + trans-9d and cis-9d (52)b | |
E | 86:14 | trans-9e (32)a + cis-9e (11)a + trans-9e and cis-9e (54)b | |
F | 78:22 | trans-9f (31)a + cis-9f (8)a + trans-9f and cis-9f (50)b |
Yield of pure isomer.
Yield of pure mixture of cis- and trans-isomers.