Table 2. Acceptor Monomer Feed Ratios of CP-CMPs with Resultant Surface Areas, Optical Band Gaps, And Fluorescence and Emission Amplifications135.
| polymer CP-CMP | acceptor (mol %) | SABET (m2 g–1) | optical band gap (eV)a | λemission (nm) solid state | λemission (nm) PEG dispersion | amplification in solid state IAD/IA | amplification in PEG dispersion IAD/IA | quantum yield (%)b |
|---|---|---|---|---|---|---|---|---|
| 0 | 660 | 2.95 | 445 | 436 | 13.4 | |||
| 3a | BT (0.1) | 731 | 2.59 | 506 | 430, 502 | 0.92 | 6.42 | |
| 3b | BT (0.5) | 592 | 2.52 | 513 | 510 | 0.64 | 2.15 | |
| 3c | BT (1) | 307 | 2.50 | 515 | 512 | 0.61 | 3.86 | 7.1 |
| 3d | BT (2) | 634 | 2.48 | 518 | 515 | 0.59 | 1.98 | |
| 3e | BT (3) | 506 | 2.42 | 524 | 515 | 0.48 | 1.15 | |
| 3f | BT (5) | 547 | 2.41 | 524 | 519 | 0.49 | 1.05 | |
| 4a | TBT (0.1) | 543 | 2.07 | 419, 586 | 429, 595 | 0.11 | 1.81 | |
| 4b | TBT (0.5) | 459 | 2.04 | 416, 603 | 422, 605 | 0.07 | 0.84 | |
| 4c | TBT (1) | 544 | 2.00 | 415, 611 | 416, 610 | 0.06 | 0.62 | 1.82 |
| 4d | TBT (2) | 540 | 1.98 | 621 | 416, 612 | 0.04 | 0.40 | |
| 4e | TBT (3) | 287 | 1.97 | 626 | 413, 613 | 0.03 | 0.29 | |
| 4f | TBT (5) | 459 | 1.95 | 630 | 415, 621 | 0.03 | 0.20 | |
| 5a | PDI (0.1) | 693 | 1.96 | 450, 590 | 440 | 0.07 | ||
| 5b | PDI (0.5) | 650 | 1.94 | 424, 618 | 424 | 0.042 | 2.02 | |
| 5c | PDI (1) | 637 | 1.90 | 451, 633 | 421, 613 | 0.041 | 1.22 | 1.29 |
| 5d | PDI (2) | 656 | 1.88 | 641 | 417, 627 | 0.037 | 0.96 | |
| 5e | PDI (3) | 583 | 1.87 | 649 | 408, 630 | 0.036 | 0.27 | |
| 5f | PDI (5) | 563 | 1.85 | 655 | 414, 636 | 0.026 | 0.49 | |
| LP0 | 2.81 | 450 | 453 | 0.43 | ||||
| LP3 | BT (1) | 2.38 | 522 | 398, 520 | 0.43 | 4.37 | 0.94 | |
| LP4 | TBT (1) | 1.90 | 448, 624 | 400, 612 | 0.14 | 1.14 | 0.15 | |
| LP5 | PDI (1) | 1.85 | 577, 643 | 400, 638 | 0.13 | 0.33 | 0.56 |
a
Calculated from the onset of the absorption spectrum in solid state.
b
The absolute quantum yields were estimated using Wrighton–Ginley–Morse’s method.