Table 3. Monomer Feed Ratios to Produce CP-CMPs and Their Surface Areas, Photophysical Properties, and H₂ Evolution Rates⁵².

	relative molar monomer ratioa
copolymer	1	2	3	4	SABET (m2 g–1)b	λem (nm)c	optical gap (eV)d	total H2 evolved (μ mol)e	H2 evolution rate (μ mol h–1)e
CP-CMP1	2	1	0	0	597	445	2.95	5	1.0 ± 0.1
CP-CMP2	2	0.99	0	0.01	682	465	2.69	8	1.4 ± 0.4
CP-CMP3	2	0.95	0	0.05	710	474	2.61	11	1.8 ± 0.2
CP-CMP4	2	0.90	0	0.10	684	483	2.54	14	2.4 ± 0.1
CP-CMP5	2	0.80	0	0.20	734	498	2.53	17	3.0 ± 0.2
CP-CMP6	2	0.60	0	0.40	726	512	2.50	15	2.6 ± 0.2
CP-CMP7	2	0.50	0	0.50	839	517	2.47	17	2.9 ± 0.2
CP-CMP8	2	0.40	0	0.60	1056	523	2.42	35	6.0 ± 0.6
CP-CMP9	2	0.20	0	0.80	762	528	2.38	69	10.9 ± 0.1
CP-CMP10	2	0	0	1	995	534	2.33	100	17.4 ± 0.9
CP-CMP11	1.9	0	0.05	1	770	535	2.24	11	2.0 ± 0.2
CP-CMP12	1.6	0	0.2	1	957	547	2.10	8	1.4 ± 0.2
CP-CMP13	1	0	0.5	1	1710	558	2.07	6	1.0 ± 0.1
CP-CMP14	0.4	0	0.8	1	1525	566	1.96	<0.5	<0.1
CP-CMP15	0	0	1	1	1218	588	1.94	<1	0.2 ± < 0.1

^aThe structures of monomers 1–4 are shown in Figure 31.

^bApparent BET surface area.

^cPhotoluminescent emission peak of polymer recorded in the solid state.

^dCalculated from the onset of the absorption spectrum.

^eReaction conditions: 100 mg polymer was suspended in 100 mL diethylamine/water solution (20 vol %) and irradiated by a 300 W Xe lamp (λ > 420 nm visible filter) for 6 h.