Table 4.
Mean of the concentration expressed as mg/g of the ellagitannins found in woods of different botanical origin after toasting.
Heat Treat | Species | Seasoning Time | Monomers | Pentosylated Monomers | Dimers | Pentosylated Dimers | Total | % Monomers ** | Ratio | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Castalagin | Vescalagin | Roburin E | Granidinin | Roburin A | Roburin D | Roburin B | Roburin C | ||||||
160–170 °C 20 min | Alternative Woods | ||||||||||||
Q. pyrenaica (E) [23] | NS, 24m | 15.2 | 14.62 | 8.8 | 4.51 | ns | 2.53 | ns | ns | 45.66 | 65 | 1 | |
Q. pyrenaica (H) [23] | 19.74 | 11.37 | 12.37 | 3.57 | ns | nd | ns | ns | 47.05 | 66 | 1.7 | ||
Q. pyrenaica (E) [16] | NS, 36m | 2.77 | 0.37 | 1.66 | 0.42 | 0.41 | 0.38 | 0.21 | 0.15 | 6.37 | 49 | 7.5 | |
Q. faginea (A) [16] | 4.68 | 0.96 | 2.27 | nd | 0.24 | 0.8 | 0.25 | 0.14 | 9.34 | 60 | 4.9 | ||
Traditional Quercus | |||||||||||||
Q. petraea Matts. [23] | NS, 24m | 22.76–20.10 | 17.61–12.62 | 10.68–2.42 | 4.34–2.10 | ns | 1.37–0.70 | ns | ns | 56.76–37.94 | 86–71 | 1.6–1.3 | |
Q. alba L. [23] | 0.44–0.37 | 5.28–1.23 | 0.17–nd | nd | ns | nd | ns | ns | 5.89–1.60 | 100–97 | 0.3–0.1 | ||
Q. petraea Matts. [16] | NS, 36m | 3.79–1.75 | 1.02–0.36 | 2.23–0.75 | 0.59–0.13 | 0.50–0.20 | 0.44–0.16 | 0.22–0.10 | 0.17–0.08 | 8.96–3.53 | 60–54 | 4.9–3.7 | |
Q. robur L. [16] | 5.44–3.60 | 1.15–0.89 | 2.39–1.80 | 0.66–0.28 | 0.47–0.41 | 0.50–0.45 | 0.20–0.17 | 0.19–0.12 | 11.00–7.72 | 58–60 | 4.7–4.0 | ||
Q. alba L. [16] | nd | nd | nd | nd | nd | nd | nd | nd | nd | nd | |||
160–170 °C 30 min | Alternative woods | NS, 24m | |||||||||||
Q. pyrenaica (G) [25] | 1.7 | 0.62 | 0.46 | 0.41 | 0.32 | 0.34 | 0.27 | 0.2 | 4.32 | 54 | 2.7 | ||
Castanea sativa (C) [25] | 4.59 | 4.32 | 1.09 | 0.15 | 0.22 | 0.06 | 0.06 | 0.02 | 10.51 | 85 | 1.1 | ||
165 °C 35 min | Alternative woods | NS, 24m | |||||||||||
Castanea sativa (B) [15] | 6.56 | 1.03 | 0.88 | 0.96 | 0.33 | 0.4 | ns | ns | 10.15 | 75 | 6.4 | ||
Medium Intensity | Alternative woods | NS | |||||||||||
Q. pyrenaica (I) [7] | 4.07 | 3.22 | ns | ns | ns | ns | ns | ns | 7.29 | ns | ns | ||
Robinia p. (A) [7] | nd | nd | ns | ns | ns | ns | ns | ns | ns | ns | ns | ||
Prunus avium (B) [7] | nd | nd | |||||||||||
Traditional Quercus | |||||||||||||
Q. petraea Matts. [7] | 3.12 | 2.4 | ns | ns | ns | ns | ns | ns | 5.52 | ns | ns | ||
Q. alba L. [7] | 0.68 | 0.78 | ns | ns | ns | ns | ns | ns | 1.46 | ns | ns | ||
185 °C 45 min | Alternative woods | NS, 24m | |||||||||||
Castanea sativa (B) [15] | 0.55 | 0.11 | nd | nd | nd | nd | ns | ns | 0.66 | 100 | 5 | ||
200 °C 140 min | Alternative woods | oven 0% IH | |||||||||||
Q. humboldtti (A) [13] | 0.03 | 0.01 | 0.01 | 0.03 | 0.00* | 0.04 | 0.00* | 0.00 | 0.12 | 33 | 3 | ||
Traditional Quercus | NS, 30m | ||||||||||||
Q. petraea Matts. [13] | 3.34–1.98 | 1.46–0.87 | 0.30–0.16 | 0.31–0.09 | 0.24–0.14* | 0.38–0.18 | 0.24–0.14* | 0.04–0.03 | 5.83–3.68 | 82–77 | 2.3 | ||
Q. alba L. [58] | 0.35 | 0.08 | 0.02 | 0.04 | 0.02* | 0.04 | 0.02* | 0.01 | 0.56 | 77 | 4.38 | ||
250–260 °C 27 min | Alternative woods | NS, 24m | |||||||||||
Q. pyrenaica (G) [23] | 7.72 | 4.81 | nd | 0.85 | ns | nd | ns | ns | 13.38 | 94 | 1.6 | ||
Q. pyrenaica (H) [23] | 17.69 | 4.9 | 4.99 | 1.75 | ns | nd | ns | ns | 29.33 | 77 | 3.6 | ||
Traditional Quercus | |||||||||||||
Q. petraea Matt. [23] | 11.60–3.93 | 12.33–6.52 | nd | 1.26–1.14 | ns | nd | ns | ns | 25.19–11.59 | 90–95 | 0.9–0.6 | ||
Q. alba L. [23] | 0.35–0.21 | 5.07–0.69 | nd | nd | ns | nd | ns | ns | 5.42–0.90 | 100 | 0.5–0.0 |
Q. pyrenaica Willd. from: (E) Álava; (G) Gerês forest of Portugal; (H) Guarda forest of Portugal; (I) Portugal. Q. faginea Lam. from: (A) Álava. Castanea sativa Mill. from: (B) France; (C) Gerês forest of Portugal. Robinia pseudoacacia L. (A). Prunus avium from: (B) central France. Q. humboldtti Bonpl. from: (A) Colombia. NS: Natural seasoning, m: months, ns: not studied compound; nd: not detected; * A and B were evaluated together ** % of the monomers in the total ellagitannins; castalagin/vescalagin ratio. IH: Internal humidity. The number superscript in the second column is the reference.