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. 2020 Mar 16;25(6):1341. doi: 10.3390/molecules25061341

Table 1.

Secondary metabolites from S. tetrasperma stem bark.

No. RT M-H m/z MS/MS Tentatively Identified Compounds
1 0.95 507 169, 345, 417 Gallic acid glucuronide-glucoside
2 1.05 133 - Malic acid
3 1.37 191 111, 173 Quinic acid
4 2.29 315 153 Protocatechuic acid 3-O-hexoside *
5 2.60 331 125, 169, 313 Gallic acid glucoside
6 2.79 447 163, 315 Coumaric acid galloyl pentoside
7 3.46 609 305, 441, 457 (epi)Gallocatechin digallate
8 5.24 593 289, 425, 575 (epi)Catechin-(epi)-gallocatechin
9 5.91 865 289, 451, 595 (epi)Catechin-(epi)catechin-(epi)catechin
10 6.55 609 305, 423, 441 (epi)Gallocatechin-(epi)-gallocatechin
11 8.46 305 179, 221, 287 (epi)Gallocatechin
12 11.82 881 289, 577, 695 (epi)Gallocatechin-(epi)catechin-(epi)catechin
13 12.81 577 289, 407, 451 (epi)Catechin-(epi)catechin #
14 13.56 577 289, 407, 451 (epi)Catechin-(epi)catechin #
15 14.16 289 179, 285, 245 Epicatechin
16 15.12 289 179, 285, 245 Catechin #
17 21.73 423 161, 285 Salicortin *
18 29.58 451 169, 313, 331 p-Hydroxy benzoyl galloyl glucose
19 30.45 435 153, 297, 315 p-Hydroxy benzoyl protocatechuic acid glucose
20 32.07 423 145, 163, 307 Grandidentatin #
21 33.26 423 145, 163, 307 Grandidentatin isomer
22 36.41 477 151, 179, 315 Isorhamnetin-3-O-glucoside
23 37.82 431 145, 163, 307 Trichocarposide *
24 38.19 431 145, 163, 307 Trichocarposide isomer
25 39.33 431 145, 163, 307 Trichocarposide isomer
26 43.23 435 179, 273 Phlorizin
27 49.29 569 307, 423, 431 Coumaroyl dihydrobenzoylsalicin *
28 5.92 631 191, 329, 353 Chlorogenic acid derivative
29 53.02 569 307, 423, 431 Coumaroyl dihydrobenzoylsalicin isomer *
30 55.21 527 155, 405 Tremulacin *
31 56.32 577 269 Terniflorin *
32 62.93 309 171, 251, 291 Fatty acid derivative
33 70.32 311 293, 311 Eicosanoic acid
34 72.48 723 269, 453, 559, 577 Coumaroyl-terniflorin
35 75.53 271 209, 253, 271 Unidentified
36 77.26 293 171, 235, 275, 293 Hydroxy-octadecatrienoic acid *
37 79.92 295 171, 277, 295 Hydroxy-octadecadienoic acid *
38 81.01 295 171, 277, 295 Hydroxy-octadecadienoic acid isomer
39 82.39 293 113, 249, 293 Hydroxy-octadecatrienoic acid isomer

* previously described in the flower extract [19] and # previously described in Salix subserata [21].