Table 3.
Complex | Eox (V) Ni2+/Ni3+ | E1/2 (V) Ni2+/Ni3+ | (Ea–Ec), mV |
---|---|---|---|
[Ni1(OAc)]+ | +1.255 | — | — |
[Ni2(OAc)]+ | — | +1.117 | 106 |
[Ni3(OAc)]+ | +1.277 | — | |
[Ni4(OAc)]+ | — | +1.077 | 106 |
[Ni5(OAc)]+ | +1.193 | 78 | |
[Ni6(OAc)]+ | +1.062 | 92 |
Complex | Eox (V) Ni2+/Ni3+ | E1/2 (V) Ni2+/Ni3+ | (Ea–Ec), mV |
---|---|---|---|
[Ni1(OAc)]+ | +1.255 | — | — |
[Ni2(OAc)]+ | — | +1.117 | 106 |
[Ni3(OAc)]+ | +1.277 | — | |
[Ni4(OAc)]+ | — | +1.077 | 106 |
[Ni5(OAc)]+ | +1.193 | 78 | |
[Ni6(OAc)]+ | +1.062 | 92 |