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. Author manuscript; available in PMC: 2021 Jan 9.
Published in final edited form as: Chem. 2019 Nov 25;6(1):142–152. doi: 10.1016/j.chempr.2019.10.022

Table 3.

Stability of Homogeneous Gold(III) Complexes vs. MOF Analogues*

graphic file with name nihms-1543523-t0004.jpg
Entry Catalyst T (°C) Additive Decomposition (%)
1 IPrAu(III)SbF6-IRMOF-10 25 TMB (10 equiv.) <5
2 IPrAu(III)PF6-bio-MOF-100 25 TMB (10 equiv.) <5
3 IPrAu(III)(biphenyl)SbF6 25 TMB (10 equiv.) 68
4 IPrAu(III)PF6-bio-MOF-100a 55 none <5
4 IPrAu(III)(Me2BPDC)SbF6a 55 none 78
*

See Supplemental Information for general reaction conditions.

a

CDCl3 used instead of CD2Cl2