Table 2.

Substrate scope for the photoredox/nickel dual‐catalyzed hydroalkylation of alkynes.^[a]

[a] Reaction conditions: alkyne (0.1 mmol), alkyl carboxylic acid (0.3 mmol), Pc4 (0.001 mmol), NiCl₂⋅dme (0.01 mmol), Cs₂CO₃ (0.1 mmol) in DMF (2.5 mL) and CH₃CN (2.5 mL) at room temperature under irradiation with a 34 W blue LED for 48 h. The values in parenthesis represent the Z/E‐ratio of the product determined by ¹H NMR analysis. [b] The reaction was performed on a 2.0 mmol scale.