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. Author manuscript; available in PMC: 2020 Sep 12.
Published in final edited form as: Chem. 2019 Aug 22;5(9):2461–2469. doi: 10.1016/j.chempr.2019.07.018

Fig. 1. Development of sterically unprotected cluster-based borylation reagents.

Fig. 1

a, General scheme for metal-catalyzed borylation using tricoordinate diborane reagents. b, Representative nucleophilic boron reagents developed previously. c, One of three triply degenerate HOMO representations of B6H62−, synthesis of the B6H71− anion, and a general borylation strategy using sterically unprotected cluster-based nucleophiles developed in this work.