. 2020 Apr 14;11:1765. doi: 10.1038/s41467-020-15558-5

Table 1.

Photophysical characteristics of TMCz-BO and TMCz-3P.

Compound	λ_abs (nm)	λ_PL (nm)	Φ_PL (%)^c	τ_p (ns)^d/τ_d (μs)^d	HOMO (eV)^e	LUMO (eV)^f	E_S/E_T (eV)^g	ΔE_ST (meV)^h	E_a (meV)ⁱ
Compound	Sol^a	Sol^a/film^b	Sol^a/film^b	τ_p (ns)^d/τ_d (μs)^d	HOMO (eV)^e	LUMO (eV)^f	E_S/E_T (eV)^g	ΔE_ST (meV)^h	E_a (meV)ⁱ
TMCz-BO	282,377	446/467	81/98	38/0.75	−5.93	−2.77	2.95/2.93	20.0	13.4
TMCz-3P	298,386	455/477	56/76	29/14.5	−5.97	−2.89	2.88/2.74	134	39.8

^aMeasured in oxygen-free toluene at room temperature (298 K).

^b30 wt% doped thin film in a host matrix (host = PPF).

^cAbsolute PLQY evaluated using an integrating sphere under a nitrogen atmosphere.

^dPL lifetimes of prompt (τ_p) and delayed (τ_d) decay components for 30 wt% doped film at 298 K.

^eDetermined by photoelectron yield spectroscopy in pure neat films.

^fDeduced from the HOMO and optical energy gap (E_g).

^gSinglet (E_S) and triplet (E_T) energies estimated from onsets of the emission spectra at 298 and 77 K in 30 wt% doped films, respectively.

^hΔE_ST = E_S − E_T.

ⁱActivation energies of RISC in 30 wt% doped films.