Results of Self-Condensing Ketyl Polymerization
Reaction conditions: monomer (1.0 g, 1.0 eq.), Mg (1.2 eq.), 1, 2-dibromoethane (0.2 eq.), THF (10 mL), 45°C, 24 h; [a]measured by GPC; [b]polymerization-induced emission.
(A) Substrate range of self-condensing ketyl polymerization.
(B) Emission digital photos of polymerization process of 2-fluorobenzophenone at different polymerization times (under irradiation with UV lamp at 365 nm).
(C) Emission digital photos of polymerization process of 4-fluorobenzophenone at different polymerization times (under irradiation with UV lamp at 365 nm).
(D) Emission digital photos of polymerization process of 4-trifluoromethylbenzophenone at different polymerization times (under irradiation with UV lamp at 365 nm).