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. 2020 Apr 1;5(14):8347–8354. doi: 10.1021/acsomega.0c00853

Table 4. Relationship between the Exchange Coupling and Structural Parameters (γ, δ) for the Co2O2 Systema.

Co–O–Co angle γ (deg) dihedral angle δ (deg) coupling
large (>97.0) very small (≈1.0) AF
small (<99.7) large (>35.3) F
larger (>99.7) any value (0–90) AF
a

F: ferromagnetic coupling, AF: antiferromagnetic coupling.