Table 2. Optical, Electrochemical, and Hole Mobility Data for Dibenzo[f,h]furazano[3,4-b]quinoxalines.

compound	Eredonseta (V)	EHOMOb/EHOMOc (eV)	ELUMOb,d/ELUMOc,d (eV)	Egoptb/Egoptc (±0.03 eV)	Absorptionb λmax (nm)/ε (103 M–1 cm–1)	hole mobilityc (10–5 cm2 V–1 s–1) (CIe 95%)	dipole momentf (D)
7a	–0.81	–7.15/–5.61	–4.29/–3.01	2.86/2.60	387/12.95	12.7 ± 1.5	6.81
					305/21.35
					294/13.52
					267/19.20
7b	–0.83	–7.12/–5.23	–4.27/–2.68	2.85/2.55	389/14.21	2.5 ± 0.5	6.87
					308/21.46
					297/15.73
					275/25.02
7c	–0.93	–6.74/–5.24	–4.17/–3.04	2.57/2.20	412/13.80	5.1 ± 0.4	8.62
					311/15.98
					279/29.98
					253/49.20
7d	–0.75	–7.11/–5.23	–4.35/–2.99	2.76/2.24	395/12.43	16.0 ± 4.0	5.43
					304/20.16
					293/12.97
7e	–0.80	–7.16/–5.27	–4.30/–2.72	2.86/2.55	386/14.73	13.3 ± 1.6	5.57
					303/20.52
					292/13.24
					275/22.76
7f	–0.75	–7.25/–5.25	–4.35/–2.80	2.90/2.45	384/11.85	2.4 ± 0.4	6.77
					307/26.34
					296/16.82
					271/18.09
7h	–0.78	–7.18/–5.27	–4.32/–2.87	2.87/2.40	384/14.54	3.5 ± 1.6	6.57
					301/16.47
					290/11.49
					267/21.02

^aE_red^onset, onset of reduction potential (vs Ag/AgCl reference electrode).

^bParameters measured in solutions at room temperature at C = 1.0 × 10^–5 M (for optical) and C = 5.0 × 10^–3 M (for electrochemical).

^cParameters measured for solid films at room temperature.

^dE_LUMO = E_HOMO – E_g^opt.

^eConfidence interval calculated from 10 replicates.

^fDFT calculation data.