TABLE 2.
LC-MS/MS method performance characteristics for 97 metabolites in dried ready-to-eat foods in Nigeria.
| Metabolites |
Granola |
Popcorn |
Metabolites |
Granola |
Popcorn |
||
| LODa | Rb | Rb | LODa | Rb | Rb | ||
| 3-Nitropropionic acid | 0.80 | 65.6 | 74.7 | Fumonisin B1 | 3.20 | 75.0 | 75.0 |
| 7-Hydroxypestalotin | 0.40 | 100.7 | 97.8 | Fumonisin B2 | 2.40 | 75.0 | 75.0 |
| Aflatoxicol | 1.00 | 97.7 | 81.8 | HT-2 toxin | 1.90 | 84.8 | 83.2 |
| Aflatoxin B1 | 0.24 | 73.8 | 70.8 | Hydrolyzed FB1 | 0.20 | 96.6 | 62.5 |
| Aflatoxin B2 | 0.40 | 74.1 | 70.4 | Ilicicolin A | 0.02 | 51.8 | 68.7 |
| Aflatoxin G1 | 0.32 | 74.8 | 64.4 | Ilicicolin B | 0.45 | 63.1 | 72.3 |
| Aflatoxin M1 | 0.40 | 83.0 | 79.3 | Ilicicolin E | 0.03 | 92.5 | 86.0 |
| Alternariol | 0.40 | 50.1 | 72.8 | Ilicolin C | 0.20 | 98.4 | 94.1 |
| Alternariolmethylether | 0.03 | 83.1 | 77.6 | Infectopyron | 20.00 | 97.1 | 80.1 |
| Ascofuranone | 0.10 | 82.8 | 83.7 | Iso-Rhodoptilometrin | 0.03 | 85.4 | 85.2 |
| Asperglaucide | 0.08 | 100.0 | 100.0 | Kojic acid | 16.00 | 70.6 | 77.6 |
| Asperphenamate | 0.04 | 100.0 | 96.8 | LL-Z 1272e | 0.03 | 90.5 | 85.4 |
| Aurofusarin | 5.00 | 99.4 | 80.1 | Linamarin | 2.50 | 85.6 | 79.3 |
| Averantin | 0.04 | 47.4 | 64.9 | Lotaustralin | 0.10 | 83.1 | 80.8 |
| Averufin | 0.04 | 98.4 | 94.7 | Macrosporin | 0.13 | 81.1 | 87.8 |
| Beauvericin | 0.10 | 100.0 | 100.0 | Methylsulochrin | 0.04 | 76.2 | 72.8 |
| Bikaverin | 8.00 | 112.3 | 77.6 | Mevinolin | 1.00 | 102.8 | 81.5 |
| Brevianamid F | 0.10 | 61.0 | 61.5 | Moniliformin | 1.60 | 64.4 | 60.4 |
| Chanoclavin | 0.08 | 82.1 | 96.2 | Monocerin | 0.06 | 98.9 | 89.0 |
| Chrysogin | 0.40 | 69.5 | 66.8 | Mycophenolic acid | 1.10 | 124.8 | 102.2 |
| Citreorosein | 0.64 | 80.6 | 77.8 | N-Benzoyl-Phenylalanine | 0.15 | 98.5 | 84.9 |
| Citrinin | 0.16 | 72.5 | 49.2 | Neoechinulin A | 1.40 | 129.5 | 63.3 |
| Culmorin | 1.60 | 107.3 | 79.2 | Nidurufin | 0.16 | 66.0 | 85.9 |
| cyclo(L-Pro-L-Tyr) | 0.80 | 61.1 | 74.0 | Nivalenol | 0.80 | 93.4 | 89.3 |
| cyclo(L-Pro-L-Val) | 0.64 | 100.0 | 100.0 | Norsolorinic acid | 0.80 | 92.7 | 108.6 |
| Cylindrol B | 0.03 | 88.0 | 82.8 | Ochratoxin A | 0.40 | 107.8 | 90.1 |
| Deoxynivalenol | 1.00 | 80.0 | 80.8 | Ochratoxin B | 0.60 | 112.3 | 90.9 |
| Dichlordiaportin | 0.60 | 113.1 | 97.6 | O-Methylsterigmatocystin | 0.12 | 96.7 | 94.6 |
| Dihydrocitrinone | 1.00 | 100.0 | 96.0 | Pestalotin | 0.40 | 106.7 | 89.8 |
| Diplodiatoxin | 2.50 | 118.6 | 93.4 | Phenopyrrozin | 1.50 | 123.4 | 109.9 |
| Emodin | 0.06 | 90.1 | 82.8 | Pinselin | 0.50 | 101.6 | 85.8 |
| Endocrocin | 5.00 | 75.6 | 63.3 | Purpactin A | 0.70 | 104.1 | 89.8 |
| Enniatin A | 0.01 | 100.0 | 101.3 | Questiomycin A | 2.00 | 114.6 | 94.9 |
| Enniatin A1 | 0.06 | 100.0 | 90.4 | Quinolactacin A | 0.08 | 75.4 | 78.6 |
| Enniatin B | 0.12 | 100.0 | 84.1 | Rugulovasine A | 7.60 | 61.0 | 71.1 |
| Enniatin B1 | 0.08 | 100.0 | 92.7 | Rugulusovin | 0.7 | 88.9 | 72.6 |
| Epiequisetin | 0.24 | 278.0 | 172.9 | Secalonic acid D | 4.00 | 114.0 | 85.4 |
| Equisetin | 0.24 | 193.3 | 151.9 | Skyrin | 0.08 | 38.3 | 56.1 |
| Ergocornine | 0.90 | 80.8 | 57.3 | Sterigmatocystin | 0.10 | 93.3 | 84.1 |
| Ergocristine | 0.40 | 124.9 | 79.3 | T-2 toxin | 0.80 | 100.8 | 87.2 |
| Ergocristinine | 0.25 | 94.1 | 74.1 | Tentoxin | 0.10 | 107.7 | 101.6 |
| Ergometrine | 1.10 | 100.0 | 104.7 | Tenuazonic acid | 10.00 | 240.1 | 189.1 |
| Ergometrinine | 0.03 | 84.1 | 85.8 | Terphenyllin | 2.00 | 90.8 | 70.5 |
| Ergotamine | 0.90 | 71.9 | 73.0 | Territrem B | 0.60 | 113.4 | 88.8 |
| Ergotaminine | 0.40 | 61.7 | 55.3 | Tryptophol | 4.00 | 76.9 | 62.1 |
| Fallacinol | 0.10 | 73.4 | 76.5 | Versicolorin A | 0.24 | 78.5 | 85.1 |
| Fellutanine A | 1.00 | 100.0 | 94.3 | Versicolorin C | 0.24 | 68.7 | 89.5 |
| Flavoglaucin | 0.24 | 100.0 | 100.0 | Zearalenone | 0.20 | 84.1 | 77.9 |
| Fumonisin A1 | 3.20 | 75.0 | 75.0 |
aLimit of detection: expressed as μg/kg sample; S/N = 3:1. bRecovery from spiking food samples (n = 5). LC-MS/MS performance parameters for garri are as given in Abass et al. (2017).