Table 2.
Comparison of the kapp, Ea, ∆S# and ∆H# values of previously reported catalysts for reduction of MO.
| Entry | Catalyst | kapp (min−1) | Ea (kJ/mol) | ∆S# (J/mol.K) | ∆H# (kJ/mol) | Ref. |
|---|---|---|---|---|---|---|
| 1 | CSIOAga | 6 * 10−4 (s−1) | 76.10 | −29.20 | 73.60 | 32 |
| 2 | IOAgb | NR | 102.4 | +41 | 99.9 | 32 |
| 3 | CuO nanostructure (35 °C) | 1 * 10−2 | 59.84 | −96.20 | 57.20 | 33 |
| 4 | Co:La:TiO2 (30 ºC) | 7.72 * 10−3 | NR | −69.15 | 35.33 | 34 |
| 5 | TiO2 (30 ºC) | 5.26 * 10−3 | NR | −69.76 | 24.07 | 34 |
| 6 | Fe3O4/Hal-Mel-TEA(IL)-Pd | 4.5 * 10−2 (s−1) | 42.02 | −139.06 | 39.40 | This work |
a: Ag-coated chitosan-capped γ-Fe2O3
b: CSIOAg catalyst without chitosan
NR: Not reported.