Table 1.
Sample | Number | [M − H]− | RT | MSn Fragments | Names of the Suggested Structures |
---|---|---|---|---|---|
PiHE | 1 | 191 | 18.80 | 173, 111, 85 | Quinic acid |
2 | 429 | 18.61 | 267 | Ononin | |
3 | 431 | 18.43 | 295, 269 | Vitexin | |
4 | 447 | 18.24 | 429, 419, 285, 151 | Orientin | |
5 | 555 | 17.42 | 429, 401, 295, 267 | Fukugentin | |
6 | 573 | 16.33 | 447, 420, 419, 403, 296, 269,268 | NI | |
7 | 717 | 14.31 | 591, 565, 555, 429, 403, 401, 295, 267 | Fukugiside | |
8 | 761 | 12.49 | 634, 608, 431 | NI | |
9 | 777 | 10.35 | 447 | NI | |
10 | 1111 | 9.53 | 571, 537, 509, 429 | Fukugentin dimer | |
11 | 1113 | 8.04 | 555, 429 | Fukugentin dimer | |
12 | 1129 | 6.14 | 1111, 1003, 877, 555, 429 | Fukugentin dimer | |
13 | 1131 | 5.40 | 555, 429 | NI | |
14 | 1275 | 1.39 | 718, 429 | NI | |
DCMF | 15 | 573 | 8.34 | 557, 431, 295, 269 | NI |
16 | 555 | 9.12 | 431, 429, 295, 269 | Fukugentin | |
17 | 429 | 9.56 | 429, 403, 295 | Ononin | |
18 | 561 | 10.10 | 539, 429, 413, 387 | NI | |
EAF | 19 | 573 | 6.40 | 447, 419, 269 | NI |
20 | 717 | 6.62 | 657, 635, 555, 429 | Fukugiside | |
21 | 429 | 6.69 | 295, 269 | Ononin | |
22 | 555 | 7.90 | 429 | Fukugentin | |
23 | 1134 | 13.34 | 623, 555, 429, 299, 225 | NI |
Legend: PiHE, Platonia insignis hydroalcoholic extract; DCMF, dichloromethane fraction; EAF, ethyl acetate fraction; NI, not identified.