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. 2020 Mar 31;22(8):3176–3179. doi: 10.1021/acs.orglett.0c00935

Scheme 3. Synthesis of Diterpene-Benzoate Macrolide 19 (P = Et) Pertinent to the Bromophycolide Family of Natural Products (cf. Structure of Bromophycolide A, Boxed, Bottom Left).

Scheme 3

MNBA = 2-methyl-6-nitrobenzoic anhydride; DMAP = 4-dimethylaminopyridine.