Skip to main content
. 2020 Apr 2;59(8):5564–5578. doi: 10.1021/acs.inorgchem.0c00263

Figure 6.

Figure 6

Cathodic IR spectroelectrochemistry at R2′ as [Re(3,3′-DHBPY-H+)(CO)3Cl](↓) undergoes 1e reductive deprotonation to transient [Re(3,3′-DHBPY-2H+)(CO)3Cl]2– (↑↓) and its concomitant decay to [Re(3,3′-DHBPY-2H+)(CO)3]3– (↑). Conditions: an OTTLE cell, THF/Bu4NPF6, T = 298 K. The label ■ corresponds to an unassigned side product.