Table 2.

Experimental POAV angles and bowl depths of 5b at the specific focused carbons.

molecule	POAV angle φ/°				bowl depth/Å
					benzylic		aromatic
5b	C1 C2 C3a	6.5 6.7 6.7	C3b C4	7.6 7.3	C6 C9	0.84 0.80	C6 C7A C8B	0.81 0.89 0.88	C9 C11 C12	0.80 0.89 0.84

^aCalculated using C4–C3–C8A, C8A–C3–C2, C2–C3–C4; ^bcalculated using C4–C3–C7B, C7B–C3–C2, C2–C3–C4.