Table 2.

Values of the binding constants of silver(I) complexes 1–3 with ctDNA.

Complex	UV-Vis titration		Fluorescent titration
	K b (M−1)	ΔGo (kcal/mol)	K sv (M−1)	Hypochromism (%)	К q (M−1·s−1)	K A (M−1)	n
1	6.65.105	−7.9	(2.53 ± 0.21).103	11.3	2.53.1011	1.8.104	1.40
2	4.58.105	−7.7	(2.39 ± 0.51).103	12.0	2.39.1011	4.22.104	0.80
3	6.105	−7.8	(9.07 ± 0.70).102	3.8	9.07.1010	59.16	0.72