Table 1. Role of Support on Au NPs Catalyzed Aerobic Oxidation of Alcoholsa.
entry | catalyst | Au particle size (nm) | product yield (%)c |
---|---|---|---|
1 | Au/HT | 2.7 | 99 |
2 | Au/MgO | 3.1 | 71 |
3 | Au/Al2O3 | 3.6 | 71 |
4 | Au/TiO2 | 3.7 | 14 |
5 | Au/TiO2 + Na2CO3c | 3.7 | 65 |
6 | Au/SiO2 | 14.0 | <1 |
Reproduced with permission from ref (253). Copyright 2016 Wiley-VCH.
Reaction conditions: Au catalyst (0.45 mol %), 1-phenylethanol (1 mmol), toluene (5 mL). Determined by GC analysis.
Reaction conditions: Au catalyst (0.45 mol %), 1-phenylethanol (1 mmol), toluene (5 mL). Na2CO3 (3 mmol).