Scheme 4.

Comparison of uni‐ and bimolecular radical‐forming reactions involving benzyl hydroperoxide (23; enthalpy values relative to the reactants are in kJ mol−1; distances are in pm, and angles in degrees).34

Comparison of uni‐ and bimolecular radical‐forming reactions involving benzyl hydroperoxide (23; enthalpy values relative to the reactants are in kJ mol−1; distances are in pm, and angles in degrees).34