Table 4.
CO and CN stretching frequencies (cm−1) of IR-spectroscopically observed HtSH [NiFe] active site species.
Assignment | ν(CO) | ν(CN) | |
---|---|---|---|
n/aa | 1993 | 2081 | 2090 |
Nir-B-like | 1964 | 2087 | 2098 |
Nir-S | 1936 | 2058 | 2071 |
Nia-S | 1951 | 2076 | 2089 |
Nia-C | 1971 | 2076 | 2089 |
Nia-SR | 1958 | 2062 | 2076 |
Nia-SR’ | 1943 | 2048 | 2062 |
Nia-SR” | 1934 | 2048 | 2062 |
Not assigned. Oxidized active site species of unknown structure