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. 2020 Apr 13;5(16):9142–9150. doi: 10.1021/acsomega.9b04361

Table 2. Oligomerization of α-Olefin and Proportions of Dimersa.

α-olefin conv. after 3 h, (%) dimer in products (wt %)b dimer in the separator (wt %)c 1-olefin in the dimer (wt %)d 1-olefin in the separator (wt %)e
1-decene 83.4 82.9 96.4 91.7 88.4
a

Reactionconditions: α-olefin, 50 mL; metallocene catalyst, 90 μmol; nAl/nZr= 50:1; T, 80 °C; and t, 3 h.

b

Determined by GC.

c

Determined by GC.

d

Determined by 13C NMR spectrocopy.

e

e = c × d.