Table 2. Oligomerization of α-Olefin and Proportions of Dimersa.
α-olefin | conv. after 3 h, (%) | dimer in products (wt %)b | dimer in the separator (wt %)c | 1-olefin in the dimer (wt %)d | 1-olefin in the separator (wt %)e |
---|---|---|---|---|---|
1-decene | 83.4 | 82.9 | 96.4 | 91.7 | 88.4 |
Reactionconditions: α-olefin, 50 mL; metallocene catalyst, 90 μmol; nAl/nZr= 50:1; T, 80 °C; and t, 3 h.
Determined by GC.
Determined by GC.
Determined by 13C NMR spectrocopy.
e = c × d.