Table 1.
Characteristic 1H NMR data (δH (J in Hz)) for talaumidin (1) and its diastereomers 1a−1g.
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Positions | 1 | 1a | 1b | 1c | 1d | 1e | 1f | 1g |
6 and 7 | 1.02 (5.8) | 0.67 (7.0) | 0.62 (7.3) | 1.02 (6.6) | 0.61 (7.1) | 0.59 (6.1) | 0.68 (6.5) | 0.65 (6.8) |
1.02 (5.8) | 1.04 (6.6) | 0.99 (6.2) | 1.02 (6.6) | 1.00 (6.6) | 0.61 (6.1) | 0.69 (6.5) | 1.04 (6.6) | |
3 and 4 | 1.76 (m) | 1.75 (m) | 2.43 (m) | 2.28 (m) | 2.42 (m) | 2.65 (m) | 2.25 (m) | 1.74 (m) |
1.76 (m) | 2.23 (m) | 2.43 (m) | 2.28 (m) | 2.42 (m) | 2.65 (m) | 2.25 (m) | 2.21 (m) | |
2 and 5 | 4.61 (9.1) | 4.36 (9.3) | 4.63 (9.3) | 4.45 (6.4) | 4.62 (9.3) | 5.09 (6.4) | 5.40 (6.0) | 4.36 (9.3) |
4.61 (9.1) | 5.09 (8.8) | 5.43 (4.0) | 4.46 (6.7) | 5.43 (4.4) | 5.09 (6.4) | 5.40 (6.0) | 5.10 (8.5) |