Table 2.
The Effect of added anion and cation on the rate of reaction of [CoSalophen]+ and LSH at [CoSalophen+] = 2.0 10−4 mol/dm3, [LSH] = 12.0 × 10−3 mol/dm3, [H+] = 1.0 × 10−3 mol/dm3, μ = 0.1 C2 mol/dm3, T = 27 ± 1, and λmax = 470 nm.
| [Z] | 103 [Z], (mol/dm3) | 103 k1, (/s) | 101 k2, (dm3/mol/s) | |
|---|---|---|---|---|
| SO42- | 0.0 | 8.20 | 6.83 | |
| 3.0 | 8.39 | 6.99 | ||
| 6.0 | 8.59 | 7.16 | ||
| 9.0 | 8.67 | 7.22 | ||
| 12.0 | 8.78 | 7.31 | ||
| 15.0 | 8.95 | 7.45 | ||
| 18.0 | 9.10 | 7.58 | ||
| Ca2+ | 0.0 | 8.20 | 6.83 | |
| 3.0 | 7.14 | 5.95 | ||
| 6.0 | 5.56 | 4.63 | ||
| 9.0 | 4.14 | 3.45 | ||
| 12.0 | 3.48 | 2.90 | ||
| 15.0 | 2.55 | 2.13 | ||
| 18.0 | 0.94 | 0.79 | ||