Table 3.
Temperature dependent rate constants and activation parameters for the redox reaction of [CoSalophen]+ and LSH at [CoSalophen+] = 2.0 10−4 mol/dm3, [LSH] = 12.0 × 10−3 mol/dm3, [H+] = 1.0 × 10−3 mol/dm3, μ = 0.1C2 mol/dm3, T = 27 ± 1, and λmax = 470 nm.
| T (K) | 103 k1 (/s) | 101 k2 (dm3/mol/s) |
|---|---|---|
| 300 | 8.20 | 6.83 |
| 305 | 12.41 | 10.34 |
| 310 | 15.13 | 12.61 |
| 315 | 15.25 | 12.70 |
| 320 | 18.82 | 15.68 |
| 325 |
22.57 |
18.81 |
| Activation parameters | ||
| ΔHǂ = +28 kJ/mol | ΔSǂ = -158 J/mol/K | |
| ΔGǂ = +74 kJ/mol at 300 K | Ea = +29 kJ/mol | |