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. 2020 Apr 30;6(4):e03850. doi: 10.1016/j.heliyon.2020.e03850

Table 3.

Temperature dependent rate constants and activation parameters for the redox reaction of [CoSalophen]+ and LSH at [CoSalophen+] = 2.0 × 10−4 mol/dm3, [LSH] = 12.0 × 10−3 mol/dm3, [H+] = 1.0 × 10−3 mol/dm3, μ = 0.1C2 mol/dm3, T = 27 ± 1°C, and λmax = 470 nm.

T (K) 103 k1 (/s) 101 k2 (dm3/mol/s)
300 8.20 6.83
305 12.41 10.34
310 15.13 12.61
315 15.25 12.70
320 18.82 15.68
325
22.57
18.81
Activation parameters
ΔHǂ = +28 kJ/mol ΔSǂ = -158 J/mol/K
ΔGǂ = +74 kJ/mol at 300 K Ea = +29 kJ/mol