Experiments were carried out at 100 K with Mo Kα radiation using a Bruker D8 Venture diffractometer. Absorption was corrected for by multi-scan methods (SADABS; Bruker, 2016 ▸), except for (IIa) and (IIe), where TWINABS (Bruker, 2012) was used.
(Ic) | (Id) | (Ie) | |
---|---|---|---|
Crystal data | |||
Chemical formula | C24H21NO4 | C25H24N2O3 | C22H18N2O3 |
M r | 387.42 | 400.46 | 358.38 |
Crystal system, space group | Monoclinic, C2/c | Triclinic, P
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Triclinic, P
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a, b, c (Å) | 18.7572 (14), 13.2095 (10), 16.750 (2) | 9.1028 (8), 10.6434 (9), 11.2539 (10) | 7.8838 (5), 10.1766 (8), 11.8719 (9) |
α, β, γ (°) | 90, 105.374 (5), 90 | 88.988 (3), 68.422 (3), 81.352 (3) | 87.554 (3), 75.996 (2), 69.428 (2) |
V (Å3) | 4001.7 (6) | 1001.55 (15) | 864.30 (11) |
Z | 8 | 2 | 2 |
μ (mm−1) | 0.09 | 0.09 | 0.09 |
Crystal size (mm) | 0.14 × 0.13 × 0.10 | 0.23 × 0.19 × 0.16 | 0.25 × 0.16 × 0.06 |
Data collection | |||
T min, T max | 0.908, 0.991 | 0.946, 0.986 | 0.949, 0.994 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 18506, 4768, 3469 | 41110, 4590, 4033 | 55488, 4333, 3760 |
R int | 0.051 | 0.037 | 0.045 |
(sin θ/λ)max (Å−1) | 0.659 | 0.650 | 0.670 |
Refinement | |||
R[F 2 > 2σ(F 2)], wR(F 2), S | 0.047, 0.110, 1.02 | 0.038, 0.098, 1.05 | 0.038, 0.101, 1.07 |
No. of reflections | 4768 | 4590 | 4333 |
No. of parameters | 266 | 276 | 247 |
No. of restraints | 0 | 0 | 0 |
H-atom treatment | H atoms treated by a mixture of independent and constrained refinement | H atoms treated by a mixture of independent and constrained refinement | H atoms treated by a mixture of independent and constrained refinement |
Δρmax, Δρmin (e Å−3) | 0.30, −0.26 | 0.30, −0.22 | 0.41, −0.22 |