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. 2020 Apr 20;76(Pt 5):433–445. doi: 10.1107/S2053229620004143

Experiments were carried out at 100 K with Mo Kα radiation using a Bruker D8 Venture diffractometer. Absorption was corrected for by multi-scan methods (SADABS; Bruker, 2016), except for (IIa) and (IIe), where TWINABS (Bruker, 2012) was used.

  (Ic) (Id) (Ie)
Crystal data
Chemical formula C24H21NO4 C25H24N2O3 C22H18N2O3
M r 387.42 400.46 358.38
Crystal system, space group Monoclinic, C2/c Triclinic, P Inline graphic Triclinic, P Inline graphic
a, b, c (Å) 18.7572 (14), 13.2095 (10), 16.750 (2) 9.1028 (8), 10.6434 (9), 11.2539 (10) 7.8838 (5), 10.1766 (8), 11.8719 (9)
α, β, γ (°) 90, 105.374 (5), 90 88.988 (3), 68.422 (3), 81.352 (3) 87.554 (3), 75.996 (2), 69.428 (2)
V3) 4001.7 (6) 1001.55 (15) 864.30 (11)
Z 8 2 2
μ (mm−1) 0.09 0.09 0.09
Crystal size (mm) 0.14 × 0.13 × 0.10 0.23 × 0.19 × 0.16 0.25 × 0.16 × 0.06
 
Data collection
T min, T max 0.908, 0.991 0.946, 0.986 0.949, 0.994
No. of measured, independent and observed [I > 2σ(I)] reflections 18506, 4768, 3469 41110, 4590, 4033 55488, 4333, 3760
R int 0.051 0.037 0.045
(sin θ/λ)max−1) 0.659 0.650 0.670
 
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S 0.047, 0.110, 1.02 0.038, 0.098, 1.05 0.038, 0.101, 1.07
No. of reflections 4768 4590 4333
No. of parameters 266 276 247
No. of restraints 0 0 0
H-atom treatment H atoms treated by a mixture of independent and constrained refinement H atoms treated by a mixture of independent and constrained refinement H atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3) 0.30, −0.26 0.30, −0.22 0.41, −0.22